Saturday, December 1, 2007

Clean Coal or Dirty Coal?

When President Bush said “America is addicted to oil”, he could also have said that America is addicted to coal.

Most Americans are not aware of the sheer scale of current coal use in the United States. Over 50% of electricity is generated from coal with 20 pounds of coal per a person being burnt every day to generate electricity.

While questions are increasingly being raised about remaining oil and gas reserves, we are assured that there is plenty of coal left to burn. Indeed in a talk to a meeting of builders and contractors at the Capital Hilton on June 8, 2005 President Bush asked the audience,
"Do you realize we've got 250 million years of coal?"

Hopefully readers will spot this obvious gaffe. The figure quoted by the coal industry is 250 years of reserves, not 250 million years. The energy illiteracy of the average person is worrying enough, but in our political leadership it is a real cause for concern.

There are an estimated one trillion tons of recoverable coal in the world, by far the largest reserve of fossil fuel left on the planet. The United States has over 25% of the world’s recoverable coal reserves. An important point to remember when considering how many years of coal we have left is that these figures are based on current rates of consumption and do no take into account growing demand for electricity. Since 1980 coal use for power generation has increased by over 75%.

A good percentage of the coal that’s left is too dirty to be burned in conventional power plants and much of its buried in inconvenient places. In 1974 the USGS published an estimate of the recoverable reserve base at 243 billion tons. This however failed to take into account real world restrictions on mining: state and national parks, roads, towns, proximity to railroads, coal quality, losses during mining and geologic limitations. When these are factored in less than 50% of the coal estimated as “recoverable” in the 1974 study was available for mining. This fails to taken into account how much is economically recoverable at market prices. In a 1989 study by the U.S. Bureau of Mines in Kentucky, at $30 a ton 22% of coal was economically recoverable. The author Tim Rohrbacher wrote “a strong argument can be made that traditional coal producing regions may soon be experiencing resource depletion problems far greater and much sooner than previously thought”.

Recently there has been a rise in suggestions that America should replace its addiction to oil, with diesel fuel made from American coal. There is currently in place a Coal-to-Liquids Tax Credit of $0.50/gallon in place until 2023. The idea has been around for a long while, in the second world war it was used by the Germans to make Nazi oil from coal when their supply of normal gasoline was cut off. I remember when I first started researching peak oil I realised after awhile if things got bad that coal rich countries might turn to making Nazi oil in desperation when petroleum depletion started to bite. Of course calls to start building Coal to Liquids plants aren’t proof that petroleum depletion is well advanced, but I hardly see it as a source for optimism.


Fischer-Tropsch pilot plant

You don’t need to be an expert on coal liquefaction to realise that it’s a bad idea as this article on AutoblogGreen shows. It’s expensive, uses lots of water, produces double the carbon dioxide when compared to regular petroleum use and produces diesel when the vast majority of the U.S. car fleet runs on gasoline. Over at the Ergosphere, the Engineer Poet crunches the numbers and compares coal to liquids versus electric vehicles. He calculates that to replace the United States petroleum consumption at current rates would take 214 four billion dollar coal to liquid plants (that’s not far off a trillion dollars in investment) and the mining of an additional one and a half billion tons of coal a year, in addition to the one billion tons already being mined for electricity generation. It should be noted that the high percentage of electricity currently produced from coal is not an argument against electric vehicles, this is something I have covered in detail elsewhere on this blog. Electric motors are inherently more efficient than the internal combustion engine. It is far easier to control emissions from large power plant, than from the exhausts of thousands of cars. Electric vehicles are not reliant on one source of energy and in the longer term polluting non-renewable sources of electricity can be replaced by clean alternative energy.

The coal industry’s promotion of the idea that America has a vast reserve of coal is slowing the transition to clean renewable sources of energy. In addition to tv spots showing child actors extolling the virtues of coal, the industry has spent heavily to get the ear of the political establishment. According to the Center for Responsive Politics, Peabody Energy, the world’s largest coal company spent over 5% of its revenues on political contributions, for comparison Exxon Mobil and General Motors spent a fraction of one percent.

In seeming return for such generosity, The Energy Policy Act of 2005 included five billion dollars of subsidies for the coal industry.

Virtually every power plant built in America between 1975 and 2002 was fired by natural gas. However between 1970 and 2000, the amount of coal America used to generate electricity tripled.

Now with natural gas prices rising steeply, U.S. power utilities are expected to build the equivalent of 280 500 megawatt coal-fired electricity power plants between 2003 and 2030. China is already constructing the equivalent of one large coal burning power plant a week with two thirds of energy production coming from dirty coal. 16 of the 20 most polluted cities in the world are in China. India is the third largest producer of coal in the world, also getting over two thirds of its energy from coal. If these new coal plants are built, they will add as much carbon dioxide to the atmosphere as has been released by all the coal burned in the last 250 years.


Acid run off from coal mining

Coal’s sale price may be low, but the true costs of its extraction, processing and consumption are high. Our use of coal leads to ravaged mountains, air pollution from acidic and toxic emissions and fouled water supplies. Coal mining is massively more invasive than oil or gas drilling. Coal burning power plants account for more than two-thirds of sulfur dioxide, 22% of nitrogen oxides, nearly 40% of carbon dioxide and a third of all mercury emissions in the United States. Results of the largest mercury hair sampling project in the U.S. found mercury levels exceeding the EPA’s recommended limit of one microgram of mercury per gram of hair in one in five women of childbearing age tested. Each year coal plants produce about 130 million tons of solid waste, about three times more than all the municipal garbage in the U.S. The American Lung Association calculates that around 24,000 people a year die prematurely from the effects of coal fired power plant pollution.

Techniques for addressing CO2 emissions exist, although the will to quickly implement them lags.

The techniques electric utilities could apply to keep much of the carbon dioxide they produce from entering the atmosphere are known as CO2 capture or geological carbon sequestration. This involves separating the CO2 as it is created and pumping it underground to be stored.

Until recently I wasn’t aware that all the technological components needed for carbon sequestration are commercially ready (according to an article in September’s Scientific American magazine) as they have already been proven in applications unrelated to avoidance of climate change. However integrated systems have yet to be built on a commercial scale.

Capture technologies have been deployed extensively throughout the world both in the manufacture of chemicals (e.g. fertilizer) and in the purification of natural gas. Industry has gained experience with CO2 storage in operations to purify natural gas, principally in Canada, as well as using carbon dioxide to boost oil production, mainly in the United States.



The Intergovernmental Panel on Climate Change (IPCC) estimated in 2005 that it is highly likely that geologic locations worldwide are capable of sequestering at least two trillion metric tons of CO2 - more than is likely to be produced by fossil fuel consuming power plants this century.

Carbon sequestration is not without risk. The two main risks are sudden escape and gradual leakage of carbon dioxide. In 1986 at Lake Nyos in Cameroon, Africa carbon dioxide originating from a volcano killed over 1,700 people. However according to IPCC this is unlikely for engineered CO2 storage in carefully selected, deep porous geologic rock formations. In regard to gradual leakage the IPCC estimated in 2005 that in excess of 99% of carbon sequestered is “very likely” to remain in place for at least one hundred years.

Studies indicate that 85%-95% of the carbon in coal could be sequestered using existing power generation technologies.



A key point is that fundamentally different approaches to carbon capture would need to be pursued for power plants using the old pulverised coal technology as opposed to the newer integrated gasification combined cycle (IGCC). IGCC plants use heat and pressure to cook off impurities in coal and convert it into a synthetic gas, this gas is then burnt in a turbine. These plants are 10% more efficient than conventional plants, consume 40% less water, produce 50% less solid waste and burn almost as cleanly as natural gas plants.

Although building IGCC power plants is slightly more expensive (10%-20%), IGCC is likely to be the most effective and cheapest option for carbon capture.

In an IGCC plant designed to capture CO2 the syngas exiting the gasifier, after being cooled and cleaned of particles, would be reacted with steam to make a gas made up mainly of CO2 and hydrogen. The CO2 would then be extracted and pumped to a storage site. The remaining hydrogen would be burned to generate more power. Captured carbon dioxide can by piped up to several hundred miles to a suitable geologic storage site.

A recent study found that for carbon capture in a saline formation one hundred kilometers from a power plant would cost an additional 1.9 cents per kilowatt-hour (over the generation cost of 4.7 cents per kilowatt-hour for a coal IGCC plant that vents carbon dioxide), making a 40% premium. With coal generation costing 6.6 cents for a kilowatt hour, this would make wind power cheaper than coal and with technology advances could also provide a boost to other renewable energy sources (e.g. concentrating solar power).

However electricity producers are rushing to build conventional coal pulverisation power plants, just as they rushed to build coal plants without sulfur scrubbers prior to legislation coming into force. This is short-sighted as it is more expensive, more energy intensive and less effective to attempt to capture carbon from conventional coal power plants. It is highly likely that having built these plants, that the coal industry would expect the taxpayer to foot the bill for the additional expense. Of the one hundred or so plants being planned or under construction in America only a handful use IGCC technology.


Proposed Design for FutureGen

FutureGen, is the Department of Energy financed one billion dollar zero emissions plant intended to turn coal into electricity and hydrogen. Proposed in 2003 and backed by a consortium of coal and electric companies, it is not due to come online until at least 2013. Many in the industry consider this date to be dubious nicknaming the project NeverGen. It is intended to make it look like the coal industry is doing something, while actually doing very little and in the process putting off changing how coal plants are built for a decade or two. Indeed in its Coal Vision report(pdf), the industry does not plan on building “ultra-low emissions” plants on a commerical scale until between 2025 and 2035. According to the report “there is considerable debate about the need to reduce CO2 emissions”. The report also states that “achieving meaningful CO2 reductions would require significant technical advances”.

The report further states “large scale and long term demonstrations of carbon sequestration technologies over a geographically and geologically diverse range of... sites are needed before making any policy decisions concerning carbon management”. The coal industry wants sequestration to be demonstrated not only in the United States but additionally “similar assessments need to be conducted internationally”. In terms of who should pay for these demonstrations the report writes “the government must play a significant role”.

It sounds that if the coal industry has its way, it won’t be using carbon capture for many decades.

Instead of waiting until 2013 or even 2035, the coal industry could be building IGCC power plants with carbon capture now. The rush to build conventional coal pulverisation plants is extremely short sighted as these plants could be operating for the next fifty years or more.

In the first instance I advocate maximising our use of clean renewable energy. At the moment wind power is being used to generate only 0.5% of electricity in the United States. Using existing technology wind power could cost effecively generate a significant portion of many countries electricity supply. Significant sums of money should also be invested in making solar power and wave power more cost effective, as well as investments in energy long shots such as cellulosic ethanol and fusion power. If we are going to continue to use coal as global society as a major source of energy, which seems pretty much inevitable for at least the next few decades in key countries such as the United States, China & India, then we should be building IGCC power plants with carbon capture and retiring existing dirty coal plants now. If there are unforeseen problems with carbon capture, we need to find out now rather than in a few decades time. The coal industry's business as usual attitude is simply not acceptable.

Jeff Goodell in his recent book “Big Coal” concludes, “coal gives us a false sense of security, if we run out of gas and oil, we can just switch over to coal… the most dangerous things about our continued dependence on coal is it preserves the illusion that we don’t have to change our thinking”.

Further Reading:
“Big Coal” by Jeff Goodell
“What to Do About Coal?” in Scientific American September, 2006

http://alt-e.blogspot.com/

3 comments:

M. Simon said...

Speaking of resource depletion: there is no penny a pound gold available any where on earth. None. Which means of course that the people talking about mining reserves of gold are blowing smoke.

Well, enough fooloshness. Here is something that might change the energy equation quickly:

Bussard Fusion Reactor
Easy Low Cost No Radiation Fusion

It has been funded:

Bussard Reactor Funded

The above reactor can burn Deuterium which is very abundant and produces lots of neutrons or it can burn a mixture of Hydrogen and Boron 11 which does not.

The implication of it is that we will know in 6 to 9 months if the small reactors of that design are feasible.

If they are we could have fusion plants generating electricity in 10 years or less depending on how much we want to spend to compress the time frame.

BTW Bussard is not the only thing going on in IEC. There are a few government programs at Los Alamos National Laboratory, MIT, the University of Wisconsin and at the University of Illinois at Champaign-Urbana among others.

The Japanese and Australians also have programs.

Anonymous said...

Carbon To the Soil,
I thought this most ubiquitous carbon sink might interest you.

Here's the current news and links on Terra Preta (TP)soils and closed-loop pyrolysis of Biomass;



Terra Preta Soils Technology To Master the Carbon Cycle

This technology represents the most comprehensive, low cost, and productive approach to long term stewardship and sustainability.Terra Preta Soils a process for Carbon Negative Bio fuels, massive Carbon sequestration, 1/3 Lower CH4 & N2O soil emissions, and 3X Fertility Too.
Thanks,
Erich

SCIAM Article May 15 07;

http://www.sciam.com/article.cfm?articleID=5670236C-E7F2-99DF-3E2163B9FB144E40



After many years of reviewing solutions to anthropogenic global warming (AGW) I believe this technology can manage Carbon for the greatest collective benefit at the lowest economic price, on vast scales. It just needs to be seen by ethical globally minded companies.

Could you please consider looking for a champion for this orphaned Terra Preta Carbon Soil Technology.

The main hurtle now is to change the current perspective held by the IPCC that the soil carbon cycle is a wash, to one in which soil can be used as a massive and ubiquitous Carbon sink via Charcoal. Below are the first concrete steps in that direction;

S.1884 – The Salazar Harvesting Energy Act of 2007

A Summary of Biochar Provisions in S.1884:

Carbon-Negative Biomass Energy and Soil Quality Initiative

for the 2007 Farm Bill

http://www.biochar-international.org/newinformationevents/newlegislation.html

(...PLEASE!!..........Contact your Senators & Repps in Support of S.1884........NOW!!...)

Tackling Climate Change in the U.S.

Potential Carbon Emissions Reductions from Biomass by 2030by Ralph P. Overend, Ph.D. and Anelia Milbrandt
National Renewable Energy Laboratory

http://www.ases.org/climatechange/toc/07_biomass.pdf

The organization 25x25 (see 25x'25 - Home) released it's (first-ever, 55-page )"Action Plan" ; see; http://www.25x25.org/storage/25x25/documents/IP%20Documents/ActionPlanFinalWEB_04-19-07.pdf
On page 29 , as one of four foci for recommended RD&D, the plan lists: "The development of biochar, animal agriculture residues and other non-fossil fuel based fertilizers, toward the end of integrating energy production with enhanced soil quality and carbon sequestration."
and on p 32, recommended as part of an expanded database aspect of infrastructure: "Information on the application of carbon as fertilizer and existing carbon credit trading systems."

I feel 25x25 is now the premier US advocacy organization for all forms of renewable energy, but way out in front on biomass topics.



There are 24 billion tons of carbon controlled by man in his agriculture and waste stream, all that farm & cellulose waste which is now dumped to rot or digested or combusted and ultimately returned to the atmosphere as GHG should be returned to the Soil.

Even with all the big corporations coming to the GHG negotiation table, like Exxon, Alcoa, .etc, we still need to keep watch as they try to influence how carbon management is legislated in the USA. Carbon must have a fair price, that fair price and the changes in the view of how the soil carbon cycle now can be used as a massive sink verses it now being viewed as a wash, will be of particular value to farmers and a global cool breath of fresh air for us all.

If you have any other questions please feel free to call me or visit the TP web site I've been drafted to co-administer. http://terrapreta.bioenergylists.org/?q=node

It has been immensely gratifying to see all the major players join the mail list , Cornell folks, T. Beer of Kings Ford Charcoal (Clorox), Novozyne the M-Roots guys(fungus), chemical engineers, Dr. Danny Day of EPRIDA , Dr. Antal of U. of H., Virginia Tech folks and probably many others who's back round I don't know have joined.



Also Here is the Latest BIG Terra Preta Soil news;

The Honolulu Advertiser: “The nation's leading manufacturer of charcoal has licensed a University of Hawai'i process for turning green waste into barbecue briquets.”

See: http://www.honoluluadvertiser.com/apps/pbcs.dll/article?AID=2007707280348



ConocoPhillips Establishes $22.5 Million Pyrolysis Program at Iowa State 04/10/07

Glomalin, the recently discovered soil protien, may be the secret to to TP soils productivity;

http://www.ars.usda.gov/is/pr/2003/030205.htm




Here is my current Terra Preta posting which condenses the most important stories and links;

Terra Preta Soils Technology To Master the Carbon Cycle

Man has been controlling the carbon cycle , and there for the weather, since the invention of agriculture, all be it was as unintentional, as our current airliner contrails are in affecting global dimming. This unintentional warm stability in climate has over 10,000 years, allowed us to develop to the point that now we know what we did,............ and that now......... we are over doing it.

The prehistoric and historic records gives a logical thrust for soil carbon sequestration.
I wonder what the soil biome carbon concentration was REALLY like before the cutting and burning of the world's forest, my guess is that now we see a severely diminished community, and that only very recent Ag practices like no-till and reforestation have started to help rebuild it. It makes implementing Terra Preta soil technology like an act of penitence, a returning of the misplaced carbon to where it belongs.

On the Scale of CO2 remediation:

It is my understanding that atmospheric CO2 stands at 379 PPM, to stabilize the climate we need to reduce it to 350 PPM by the removal of 230 Billion tons of carbon.

The best estimates I've found are that the total loss of forest and soil carbon (combined
pre-industrial and industrial) has been about 200-240 billion tons. Of
that, the soils are estimated to account for about 1/3, and the vegetation
the other 2/3.

Since man controls 24 billion tons in his agriculture then it seems we have plenty to work with in sequestering our fossil fuel CO2 emissions as stable charcoal in the soil.

As Dr. Lehmann at Cornell points out, "Closed-Loop Pyrolysis systems such as Dr. Danny Day's are the only way to make a fuel that is actually carbon negative". and that " a strategy combining biochar with biofuels could ultimately offset 9.5 billion tons of carbon per year-an amount equal to the total current fossil fuel emissions! "

Terra Preta Soils Carbon Negative Bio fuels, massive Carbon sequestration, 1/3 Lower CH4 & N2O soil emissions, and 3X FertilityToo


This some what orphaned new soil technology speaks to so many different interests and disciplines that it has not been embraced fully by any. I'm sure you will see both the potential of this system and the convergence needed for it's implementation.

The integrated energy strategy offered by Charcoal based Terra Preta Soil technology may
provide the only path to sustain our agricultural and fossil fueled power
structure without climate degradation, other than nuclear power.

The economics look good, and truly great if we had CO2 cap & trade or a Carbon tax in place.


.Nature article, Aug 06: Putting the carbon back Black is the new green:
http://bestenergies.com/downloads/naturemag_200604.pdf

Here's the Cornell page for an over view:
http://www.css.cornell.edu/faculty/lehmann/biochar/Biochar_home.htm

University of Beyreuth TP Program, Germany http://terrapreta.bioenergylists.org/?q=taxonomy/term/118

This Earth Science Forum thread on these soils contains further links, and has been viewed by 19,000 self-selected folks. ( I post everything I find on Amazon Dark Soils, ADS here):
http://forums.hypography.com/earth-science/3451-terra-preta.html



There is an ecology going on in these soils that is not completely understood, and if replicated and applied at scale would have multiple benefits for farmers and environmentalist.

Terra Preta creates a terrestrial carbon reef at a microscopic level. These nanoscale structures provide safe haven to the microbes and fungus that facilitate fertile soil creation, while sequestering carbon for many hundred if not thousands of years. The combination of these two forms of sequestration would also increase the growth rate and natural sequestration effort of growing plants.


The reason TP has elicited such interest on the Agricultural/horticultural side of it's benefits is this one static:

One gram of charcoal cooked to 650 C Has a surface area of 400 m2 (for soil microbes & fungus to live on), now for conversion fun:

One ton of charcoal has a surface area of 400,000 Acres!! which is equal to 625 square miles!! Rockingham Co. VA. , where I live, is only 851 Sq. miles

Now at a middle of the road application rate of 2 lbs/sq ft (which equals 1000 sqft/ton) or 43 tons/acre yields 26,000 Sq miles of surface area per Acre. VA is 39,594 Sq miles.

What this suggest to me is a potential of sequestering virgin forest amounts of carbon just in the soil alone, without counting the forest on top.

To take just one fairly representative example, in the classic Rothampstead experiments in England where arable land was allowed to revert to deciduous temperate woodland, soil organic carbon increased 300-400% from around 20 t/ha to 60-80 t/ha (or about 20-40 tons per acre) in less than a century (Jenkinson & Rayner 1977). The rapidity with which organic carbon can build up in soils is also indicated by examples of buried steppe soils formed during short-lived interstadial phases in Russia and Ukraine. Even though such warm, relatively moist phases usually lasted only a few hundred years, and started out from the skeletal loess desert/semi-desert soils of glacial conditions (with which they are inter-leaved), these buried steppe soils have all the rich organic content of a present-day chernozem soil that has had many thousands of years to build up its carbon (E. Zelikson, Russian Academy of Sciences, pers. comm., May 1994). http://www.esd.ornl.gov/projects/qen/carbon1.html




All the Bio-Char Companies and equipment manufactures I've found:

Carbon Diversion
http://www.carbondiversion.com/


Eprida: Sustainable Solutions for Global Concerns
http://www.eprida.com/home/index.php4

BEST Pyrolysis, Inc. | Slow Pyrolysis - Biomass - Clean Energy - Renewable Ene
http://www.bestenergies.com/companies/bestpyrolysis.html


Dynamotive Energy Systems | The Evolution of Energy
http://www.dynamotive.com/

Ensyn - Environmentally Friendly Energy and Chemicals
http://www.ensyn.com/who/ensyn.htm

Agri-Therm, developing bio oils from agricultural waste
http://www.agri-therm.com/

Advanced BioRefinery Inc.
http://www.advbiorefineryinc.ca/

Technology Review: Turning Slash into Cash
http://www.technologyreview.com/Energy/17298/


3R Environmental Technologies Ltd. (Edward Someus)
WEB: http://www.terrenum.net/

The company has Swedish origin and developing/designing medium and large scale carbonization units. The company is the licensor and technology provider to NviroClean Tech Ltd British American organization WEB: http://www.nvirocleantech.com and VERTUS Ltd.
http://www.vertustechnologies.com

The International Agrichar Initiative (IAI) conference held at Terrigal, NSW, Australia in 2007. ( http://iaiconference.org/home.html ) ( The papers from this conference are now being posted at their home page)
.

If pre-Columbian Kayopo Indians could produce these soils up to 6 feet deep over 15% of the Amazon basin using "Slash & CHAR" verses "Slash & Burn", it seems that our energy and agricultural industries could also product them at scale.

Harnessing the work of this vast number of microbes and fungi changes the whole equation of energy return over energy input (EROEI) for food and Bio fuels. I see this as the only sustainable agricultural strategy if we no longer have cheap fossil fuels for fertilizer.

We need this super community of wee beasties to work in concert with us by populating them into their proper Soil horizon Carbon Condos.




Erich J. Knight
Shenandoah Gardens
1047 Dave Berry Rd.
McGaheysville, VA. 22840
(540) 289-9750
shengar@aol.com

Journal Global Warming said...

Thanks for your visite